You may have damaged the LEDS.
To drop 4.5 volts with 33 ohm resistor requires a current of 136 mA.
That is 36% more than its maximum rating of 100 mA.
The correct value for 4.5v drop for 50 mA to 75 mA is: 90 ohms to 60 ohms.
A 33 ohm resistor in a series wired LED circuit with a 6 v power supply would have been a current of 45 mA. This is what you probably wanted.